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REGIOSELECTIVE NITRATION OF ANILINES WITH FE(NO3)3·9H2O AS A PROMOTER AND A NITRO SOURCE

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Regioselective nitration of anilines with Fe(NO3)3·9H2O as a promoter & a nitro source†

* Corresponding authors

a School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou, trung quốc E-mail: gaoyang

An efficient Fe(NO3)3·9H2O promoted ortho-nitration reaction of aniline derivatives has been developed. This reaction may go through a nitrogen dioxide radical (NO2˙) intermediate, which is generated by the thermal decomposition of iron(III) nitrate. The practicality of the present method using nontoxic & inexpensive iron reagents has been shown by the broad substrate scope và applications.

Regioselective nitration of anilines with Fe(NO3)3·9H2O as a promoter and a nitro source

Y. Gao, Y. Mao, B. Zhang, Y. Zhan and Y. Huo, Org. Biomol. Chem., 2018,16, 3881 DOI: 10.1039/C8OB00841H

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